Catalytic oxidative degradation of Orange G dye: the effect of different reaction parameters

Abstract

Catalytic oxidative degradation of a textile dye Orange G was investigated in the reaction system where oxidant Oxone® was used as a source of SO4˙ˉ anion radicals. Cobalt-doped alumina was tested as a heterogenous catalysts for Oxone® activation. The catalyst was synthetized and calcined at 500 °C. The influence of different reaction parameters was followed: the Oxone® dosage, Orange G concentration and initial pH of the reaction solution. The Oxone® dosage was varied from 10 mg to 80 mg. Small differences in degradation efficiency were observed but mass of 40 mg of Oxone® was found to be optimal in the first hour of the reaction. The effect of the Orange G concentration was investigated in the range from 20 mg dm-3 to 50mg dm-3. For the concentration of 20 mg dm-3 the reaction was much faster than for other investigated concentrations. The effect of the pH was tested in the range from 2 to 9. The optimal pH range was found to be between 6 and 9, but reaction was feasible also for lower pH. It can be concluded that investigated catalyst is applicable with high efficiency in the wide range of Oxone® dosages, dye concentrations and initial pH values

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