Behrends, Jan

Budden, Peter

Divitini, Giorgio

Gorman, Jeffrey

Orsborne, Sarah R. E.

Palecek, David

Panjwani, Naitik A.

Ryan, Seán T. J.

Sridhar, Akshay

Weiss, Leah R.

English

Institutional Repository of the Freie Universität Berlin

Correction to “Photogeneration of Spin Quintet Triplet−TripletExcitations in DNA-Assembled Pentacene Stacks”Sarah R. E. Orsborne, Jeffrey Gorman, Leah R. Weiss, Akshay Sridhar, Naitik A. Panjwani,Giorgio Divitini, Peter Budden, David Palecek, Seán T. J. Ryan, Akshay Rao, Rosana Collepardo-Guevara,Afaf H. El-Sagheer, Tom Brown, Jan Behrends, Richard H. Friend,* and Florian Auras*J. Am. Chem. Soc. 2023, 145 (9), 5431−5438. DOI: 10.1021/jacs.2c13743Cite This: J. Am. Chem. Soc. 2023, 145, 8271−8271 Read OnlineACCESS Metrics & More Article Recommendations *sı Supporting InformationPages 5436. In the analysis and discussion of the ESRexperiments, the definition of the quintet zero-field-splittingHamiltonian was mistakenly typed as= · · = +S D SHhD S I E S S( 2 ) ( )z z zTzfsq q23 q2 2The equation and definition of its terms should read asfollows:= · · = +S D SHhD S I E S S( 2 ) ( )z x yTzfsq q2q2 2where S is the vector of quintet spin operators, I ̂ is the 5×5identity matrix, and Ŝi is the spin operator defined along theprincipal axis i ∈ (x̂,ŷ,z)̂ of the ZFS tensor Dq, determined bythe symmetry of the underlying spin−spin interactions.This is also updated in Section K (“Theoretical quintet(S=2) zero-field splitting parameters”, page S22) of theSupporting Information.These corrections do not affect the conclusions presented inthe published article.■ ASSOCIATED CONTENT*sı Supporting InformationThe Supporting Information is available free of charge athttps://pubs.acs.org/doi/10.1021/jacs.3c02230.Experimental methods, synthetic procedures, and addi-tional spectroscopic data (updated) (PDF)Published: March 31, 2023Addition/Correctionpubs.acs.org/JACS© 2023 The Authors. Published byAmerican Chemical Society8271https://doi.org/10.1021/jacs.3c02230J. Am. Chem. Soc. 2023, 145, 8271−8271Downloaded via FREIE UNIV BERLIN on April 19, 2023 at 11:42:41 (UTC).See https://pubs.acs.org/sharingguidelines for options on how to legitimately share published articles.

Correction to “Photogeneration of Spin Quintet Triplet–Triplet Excitations in DNA-Assembled Pentacene Stacks”

https://refubium.fu-berlin.de/bitstream/fub188/38966/1/jacs.3c02230.pdf

Correction to “Photogeneration of Spin Quintet Triplet–Triplet Excitations in DNA-Assembled Pentacene Stacks”

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