We report the ground-state symmetry of the Ce 4f states in the heavy
fermion superconductor CeNi2​Ge2​, yielding anisotropic
cf-hybridization between the Ce 4f states and conducting electrons. By
analyzing linear dichroism in soft x-ray absorption and core-level hard x-ray
photoemission spectra, the 4f symmetry is determined as Σ-type
Γ7​, promoting predominant hybridization with the conducting electrons
originating from the Ge site. The band structures probed by the soft x-ray
angle-resolved photoemission indicates that the Ge 4p components contribute
to the band renormalization through the anisotropic hybridization effects,
suggesting that the control of the electronic structures of Ge orbital gives an
impact to achieve the exotic phenomena in CeNi2​Ge2​