Incoherent electronic band states in Mn substituted BaFe$_{2}$As$_{2}$

Abstract

Chemical substitution is commonly used to explore new ground states in materials, yet the role of disorder is often overlooked. In Mn-substituted BaFe$_{2}$As$_{2}$ (MnBFA), superconductivity (SC) is absent, despite being observed for nominal hole-doped phases. Instead, a glassy magnetic phase emerges, associated with the $S=5/2$ Mn local spins. In this work, we present a comprehensive investigation of the electronic structure of MnBFA using angle-resolved photoemission spectroscopy (ARPES). We find that Mn causes electron pockets to shrink, disrupting the nesting condition in MnBFA. Notably, we propose that electronic disorder, along with magnetic scattering, primarily contributes to suppressing the itinerant magnetic order in MnBFA. This finding connects the MnBFA electronic band structure properties to the glassy magnetic behavior observed in these materials and suggests that SC is absent because of the collective magnetic impurity behavior that scatters the Fe-derived excitations. Moreover, we suggest that Mn tunes MnBFA to a phase in between the correlated metal in BaFe$_{2}$As$_{2}$ and the Hund insulator phase in BaMn$_{2}$As$_{2}$.Comment: main 7 pages, 3 figures + supp 5 pages, 5 figure