Iura, Takafumi

Maki, Tomoyuki

Matsubara, Kouki

Nagashima, Hideo

Terasawa, Jun-ichi

Pre-activation of (μ_2,η^2:η^3:η^5-acenaphthylene)Ru_3(CO)_7 (1) by hydrosilanes in a small amount of dioxane provides novel convenient and useful procedures for hydrosilylation of carbonyl compounds and silane-induced ring-opening polymerization of cyclic ethers and a cyclic siloxane. The initial step of the catalytic cycle was investigated by NMR detection of products formed by the oxidative addition ofhydrosilanes to 1. A possibility for the involvement of cluster species in the catalytic cycle is discussed

松原, 公紀

マツバラ, コウキ

井浦, 貴史

イウラ, タカフミ

真木, 知之

マキ, トモユキ

寺沢, 淳一

テラサワ, ジュンイチ

永島, 英夫

ナガシマ, ヒデオ

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Practical Procedures for Hydrosilylation of Ketones and Silane-induced Ring-opening Polymerization of Cyclic Ethers by Prior Activation of the Cluster Catalyst by Hydrosilanes : Improved Synthetic Procedures and Mechanistic Implication on the Catalytically Active Species

Practical Procedures for Hydrosilylation of Ketones and Silane-induced Ring-opening Polymerization of Cyclic Ethers by Prior Activation of the Cluster Catalyst by Hydrosilanes : Improved Synthetic Procedures and Mechanistic Implication on the Catalytically Active Species

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