Graphene oxide (GO) and its reduced and functionalized forms have been attracting the interest of the
scientific community. Widely studied for its unique properties, GO finds applications in the vast and
heterogenous scenario of various research fields. When focusing on porous electrodes for capacitive
applications, GO is commonly proposed in its reduced form (rGO) for improved electrical conductivity.
Specifically, designed functionalization procedures are also used to tune the charges spontaneously
present on the surface of GO. In this context, this work reports on the investigation of few novel
functionalized GO materials proposed for capacitive deionization application. The modification of the
GO has been pursued following different strategies in order to achieve a controlled tuning of the surface
charge of the GO. The functionalized materials have been widely characterized by means of
morphological, physico-chemical and electrochemical characterization techniques. Finally, the
materials have been mixed with activated carbons and coated onto metallic current collectors to
assemble a device for capacitive deionization application. Performances of the different materials have
been compared in terms of salt adsorption and charge efficiency, proving the beneficial effect of the
presence of functionalized GO. Interestingly, the same approach and materials can also be applied for
the case of aqueous supercapacitors, since they share many features and similar working mechanism
with capacitive deionization
