A high-spin rotational band with 11 γ-ray transitions has been observed in 91Tc. The dynamical moment of inertia as well the transition quadrupole moment of 8.1-1.4/+1.9 eb measured for this band show the characteristics of a superdeformed band. However, the shape is more elongated than in the neighbouring A = 80-90 superdeformed nuclei. Theoretical interpretations of the band within the cranked Strutinsky approach based on two different Woods-Saxon potential parameterisations are presented. Even though an unambiguous configuration assignment proved difficult, both calculations indicate a larger deformation and at least three additional high-N intruder orbitals occupied compared to the lighter SD nuclei
