From graph theory and geometric probabilities to a representative width for three-dimensional detonation cells

Abstract

We present a model for predicting a representative width for the three-dimensional cells observed on detonation fronts in reactive gases. Its physical premise is that the dynamics of the transverse waves of irregular cells obeys a stochastic process both stationary and ergodic and produces the same burnt mass per unit of time as the average planar steady ZND process. Graph theory then defines an ideal cell whose grouping is equivalent to the actual 3D cellular front, geometric probabilities determine the mean burned fraction that parameterizes the model, and ZND calculations close the problem with the time-position relationship of a fluid element in the ZND reaction zone. The model is limited to detonation reaction zones whose sole ignition mechanism is adiabatic shock compression, such as those of the mixtures with H2, C3H8 or C2H4 as fuels considered in this work. Indeed, the comparison of their measured and calculated widths shows an agreement better than or within the accepted experimental uncertainties, depending on the quality of the chemical kinetic scheme used for the ZND calculations. However, the comparison for CH4:O2 mixtures shows high overestimates, indirectly confirming that the detonation reaction zones in these mixtures certainly include other ignition mechanisms contributing to the combustion process, such as turbulent diffusion. In these situations, the cell mean width derived from longitudinal soot recordings shows a very large scatter and may thus not be a relevant detonation characteristic length. The model is easily implementable as a post-process of ZND profiles and provides fast estimates of the cell width, length and reaction time.Comment: Extended versio