Abiotic molecular oxygen production -- ionic pathway from sulphur dioxide

Abstract

Molecular oxygen, O$_2$, is vital to life on Earth and possibly on other planets. Although the biogenic processes leading to its accumulation in Earth's atmosphere are well understood, its abiotic origin is still not fully established. Here, we report combined experimental and theoretical evidence for electronic-state-selective production of O$_2$ from SO$_2$, a major chemical constituent of many planetary atmospheres and one which played an important part on Earth in the Great Oxidation event. The O$_2$ production involves dissociative double ionisation of SO$_2$ leading to efficient formation of the O$_2^+$ ion which can be converted to abiotic O$_2$ by electron neutralisation. We suggest that this formation process may contribute significantly to the abundance of O$_2$ and related ions in planetary atmospheres, especially in those where CO$_2$, which can lead to O$_2$ production by different mechanisms, is not the dominant component