For a group π with unit e, we introduce and study the notion of a π-graded Hopf algebra. Then we introduce and construct a new braided monoidal category HHeYDπ over a π-graded Hopf algebra H. We introduce the notion of a π-double centralizer property and investigate this property by studying a braided π-graded Hopf algebra U(gln(V))⋉πH, where V is an n-dimensional vector space in HHeYDπ and U(gln(V)) is the braided universal enveloping algebra of gln(V) which is not the usual Hopf algebra. Finally, some examples and special cases are given