Tribological interactions between the piston groove and ring in combustion engines have a significant influence on mechanical friction losses. Based on the analysis of the distribution of forces acting on the piston, the conditions for the friction tests were selected. The research was carried out on composites reinforced with silicon carbide (SiCp), glassy carbon (GCp), and a hybrid mixture of particles (SiCp + GCp). Tribological tests were carried out under extremely unfavorable dry sliding conditions using a pin-on-block tester. The friction of coefficient and wear values of the matrix alloy, composites, and iron were compared. Profilometry was used to perform quantitative and qualitative analyses of the wear tracks formed on the tested surfaces. The effect of the presence of reinforcing particles on the geometry of working surfaces was also evaluated. The obtained results show that AlSi12CuNiMg/SiCp and AlSi12CuNiMg/SiCp + GCp composites provided satisfactory effects towards stabilizing the friction coefficient and reducing the wear of tested tribological couples. This may provide a new solution dedicated to an important system, which is the piston groove/piston ring in diesel engines