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Effect of isomer on polymer blends miscibility: A synchrotron small angle X-ray investigation
Authors
H.H. Shao Rabeony, M. Liang, K.S. Siakali-Kioufala, E. Hadjichristidis, N.
Publication date
1 January 1999
Publisher
Abstract
We use synchrotron small angle X-ray scattering (SAXS), calorimetry and cloud point measurements to investigate the thermodynamic of mixing in blends of poly(cyclohexyl acrylate) with the ortho and meta isomer of poly(bromostyrene) [P2BrS, P3BrS]. PCHA is miscible with P2BrS and P3BrS with lower critical solution temperature (LCST). Measurements of the absolute scattered intensity enable determination of the Flory-Huggins χ-parameter within the framework of the de Gennes random phase approximation. The following order is observed: χ(PCHA/P2BrS)<χ(PCHA/P3BrS). © 1998 Elsevier Science Ltd
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Last time updated on 10/02/2023