Low-molecular weight gelators (LMWG) are small molecules (Mw < ~1 kDa), which
form self-assembled fibrillar networks (SAFiN) hydrogels in water. The great
majority of SAFiN gels is described by an entangled network of self-assembled
fibers, in analogy to a polymer in a good solvent. Here, fibrillation of a
biobased glycolipid bolaamphiphile is triggered by Ca2+ or Ag+ ions, added to
its diluted micellar phase. The resulting SAFiN, which forms hydrogel above 0.5
wt%, has a ``nano-fishnet'' structure, characterized by a fibrous network of
both entangled fibers and β-sheets-like rafts, generally observed for
silk fibroin, actin hydrogels or mineral imogolite nanotubes, but generally not
known for SAFiN. This work focuses on the strength of the SAFIN gels, their
fast recovery after applying a mechanical stimulus (strain) and their unusual
resistance to temperature, studied by coupling rheology to small angle X-ray
scattering (rheo-SAXS) using synchrotron radiation. The Ca2+-based hydrogel
keeps its properties up to 55{\textdegree}C, while the Ag+-based gel shows a
constant elastic modulus up to 70{\textdegree}C, without appearance of any
gel-to-sol transition temperature. Furthermore, the glycolipid is obtained by
fermentation from natural resources (glucose, rapeseed oil), thus showing that
naturally-engineered compounds can have unprecedented properties, when compared
to the wide range of chemically derived amphiphiles