The addition of Natrium metabisulfite (Na2S2O5) in the tapioca with purpose to increase whiteness degree suitable to SNI 01-3729-1995 for small industries has been performed. The result of whiteness degree determination are 90.3 %; 91.8 %; 94.9 %; 95.7 % and 96.2 % with 0 %; 0.1 %; 0.2 %; 0.5 % and 1.0 % Na2S2O5 addition, respectively. The refinement result of X-ray diffraction profile showed that the tapioca consist of two phases, namely α-Amylose and β-D-Glucose. The observation result of scanning electron microscope showed that the tapioca with 0.2 % Na2S2O5 addition has dominated white color and the particle distribution was very uniform. We concluded that the Na2S2O5 can increase phase of β-D-Glucose so that able to prevent browning reaction in the tapioca