The nature of reduced CO2 adsorbates, as well as the mechanisms for their electro-oxidation on platinum, have been reviewed through the light of new experimental data obtained by cyclic voltammetry and by Fourier transform infrared reflectance spectroscopy. Three different “reduced” CO2 adsorbates are described as “‘ensembles”. It is suggested that they involve different extents of adsorbed entities, among which weakly bound and strongly bound hydrogen atoms play the most important role.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicada
