The surface topography of amorphous metals useful as electrocatalysts in water electrolysis, denoted as G16 (Cos50Ni25Si15Bu10) and G14 (Fe60Co20Si10B10), are studied at the gm scale with a conventional SEM, and at the nm scale with the STM. Both untreated specimens as well as those employed as electrodes for a relatively prolonged time exhibit the same microstructure with amorphous and crystalline surface regions. The microcrystallite reduced size structure, probably involving a very compact structure, appears to be of the greatest importance concerning the electrocatalytic activity of these materials.Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicada