1391-1396<span style="letter-spacing:-.2pt;mso-ansi-language:
PT-BR" lang="PT-BR">On condensation of 1-naphthylamine with 2-chlorobenzaldehyde, the Schiff
base (Z)-N-(2-chlorobenzylidene)naphthalene-1-amine (L) is formed which shows moderate fluorescence. L on interaction with Cu2+
hydrolyses back into fluorescent 1-naphthylamine and hence acts as fluorescent
chemodosimeter for Cu2+ by “off-on” mode with an ca. 18 times
enhancement in fluorescent intensity (detection limit is 10-5 M).
The other hydrolysed product,
2-chlorobenzaldehyde, forms a tris chelate complex with Cu2+,
as shown by UV/visible spectroscopy and cyclic voltammetry. The metal ions, Na+,
K+, Ca2+, Mn2+, Fe2+, Co2+,
Ni2+, Cd2+, Hg2+, Pb2+ and Ag+,
do not interfere while in the case of Zn2+, moderate interference is
observed.
</span