Metamaterials that are lightweight, stiff, strong, scalable and hydrophobic have been achieved separately through different materials and approaches, but achieving them in one material is an outstanding challenge. Here, stereolithography and pyrolysis are employed to create carbon microlattices with cubic topology and a strut width of 60–70 µm, with specific strength and stiffness of up to 468.62 MPa cm3 g−1 and 14.39 GPa cm3 g−1 at a density of 0.55 g cm−3, higher than existing microarchitected materials and approaching those of the strongest truss nanolattices. Subsequent fast Joule-heating then introduces a hierarchical nanographitic skin that enables hydrophobicity, with a water contact angle of 135 ± 2°, improving the hydrophilic response of pyrolytic carbon. As the Joule heating induced sp2-hybridization and nano-texturing predominantly affect the strut sheath, the effect on mechanical response is limited to a reduction in the distribution of compressive strength of as-pyrolyzed architectures by ~80% and the increase of the mean effective stiffness by ~15%. These findings demonstrate a technique to fabricate high strength, low density, and hydrophobic nanographite-coated carbon microlattices
