Three scenarios of large-eddy simulation (LES) were performed to examine the characteristic flow and pollutant dispersion in urban street canyons under neutral, unstable and stable thermal stratifications. Street canyons of unity aspect ratio with ground-heating or –cooling are considered. In the LESs of the thermal stabilities tested, a large primary recirculation is developed in the center core and the turbulence production is dominated at the roof level of the street canyon. The current LES results demonstrate that unstable stratification enhances the mean wind, turbulence and pollutant removal of street canyons. On the other hand, in stable stratification, which has been less investigated in the past, the ground-level mean wind and turbulence are substantially suppressed by the large temperature inversion. Whereas, the weakened recirculating wind in the street canyon results in a larger velocity gradient that increases the turbulence production at the roof level. It also slows down the turbulence being carried from the roof down to the lower street canyon. Therefore, a higher level of turbulent kinetic energy (TKE) is retained at the mid-level of the windward side in the stably stratified street canyon.postprintThe 5th International Symposium on Computational Wind Engineering (CWE2010), Chapel Hill, N.C., 23-27 May 2010