Multiplexed Covalent Patterns on Double‐Reactive Porous Coating

Abstract

We have conceptualized and demonstrated an approach based on the combination of hydrophobicity, a substrate‐independent dip coating as porous material with double residual chemical reactivities for implementing multiplexed, miniaturized and unclonable bulk‐infused patterns of different fluorophores following distinct reaction pathways. The embedded hydrophobicity (∼102°) restricted the unwanted spreading of beaded aqueous ink on the coating. The constructions of micropatterns on porous dip‐coating via ink‐jet printing or microchannel cantilever spotting offered orthogonal read‐out and remained readable even after removal of the exterior of the coating

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