By means of positron annihilation lifetime spectroscopy, we have investigated the native defects present in
Bi2Se3, which belongs to the family of topological insulators. We experimentally demonstrate that selenium vacancy defects (VSe1) are present in Bi2Se3 as-grown samples, and that their charge is delocalized as temperature increases. At least from 100 K up to room temperature both V0Se1 and V+Se1 charge states coexist. The observed charge delocalization determines the contribution of VSe1 defects to the n-type conductivity of Bi2Se3. These findings are supported by theoretical calculations, which show that vacancies of nonequivalent Se1 and Se2 selenium atoms are clearly differentiated by positron annihilation lifetime spectroscopy, enabling us to directly detect and quantify the most favorable type of selenium vacancy. In addition to open-volume defects, experimental data indicate the presence of defects that act as shallow traps, suggesting that more than one type of native defects coexist in Bi2Se3. As will be discussed, the presence of a dislocation density around 1010cm−2 could be the source of the detected shallow traps. Understanding the one-dimensional defects and the origin of the charge delocalization that leads Bi2Se3 to be an n-type semiconductor will help in the development of high-quality topological insulators based on this material.This work is supported by the Basque Government Grant No. IT-443-10 and partially supported by the Basque Government Grant No. IT-756-13, by the Spanish Ministry of
Economy and Competitiveness (MINECO) under the project TEC2014-60173, and by the Generalitat Valenciana under the projects Prometeo II 2015/004 and ISIC/2012/008. I.U. also wants to acknowledge financial support from the Basque
Government Grant No. PRE-2014-214 and J. Feuchtwanger for his technical support. V.M.-B. thanks the University of Valencia for its predoctoral fellowships. Finally, we would also like to thank BCMaterials for its economic support.Peer reviewe
