Coupling thermoelectrics (TE) with photovoltaics (PV) has emerged as an approach to solid-state solar harvesting, directly converting light and infrared heat into electricity. In this work, we compare PV-TE hybrid devices based on organic semiconductors in three different geometries: a reflection geometry, a non-contact transmission geometry, and a contact transmission geometry. The temperature rises of films of common organic thermoelectric materials, including poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS), single-walled carbon nanotubes (swCNT), and poly[2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene] (PBTTT), were measured in configurations representative of the proposed geometries. Because organic semiconductors possess broadband light absorption and low thermal conductivities, a significant rise in temperature was observed under illumination for all geometries. We find, however, that the best configuration is, in fact, the transmission contact mode because it sums two effects. Operating under 1 sun illumination, the temperature of a commercial organic PV module increased by ≈30 K, which leads to an enhancement in OPV performance compared to room temperature. After attaching a thermoelectric to the OPV module, losses from convection are reduced, and the OPV module heats up even more, further increasing its efficiency while additionally enabling thermoelectric generation. Finally, we calculate theoretical thermoelectric efficiencies for the materials and their respective power densities.The authors acknowledge financial support from the Spanish Ministry Science and Innovation through the “Severo Ochoa” Program for Centers of Excellence in R&D SEV-2015-0496 (FUNMAT) and CEX2019-000917-S (FUNFUTURE), and PGC2018-095411-B-I00 (RAINBOW) projects; from the Generalitat de Catalunya through grants 2017SGR488 and AGAUR 2018 PROD 00191; and from the European Research Council (ERC) under grant agreement no. 648901. This project has received funding from the European Union's Horizon 2020 research and innovation program under the Marie Skłodowska-Curie grant agreement no. 713673. J. P. J. has received financial support through the “la Caixa” INPhINIT Fellowship Grant for Doctoral studies at Spanish Research Centers of Excellence (Grant code: LCF/BQ/IN17/11620035), “la Caixa” Banking Foundation (ID100010434), Barcelona, Spain. O. Z. A. acknowledges CONACYT-SENER for his PhD scholarship (no. 472571). J. P. J. acknowledges the departments of Physics, Chemistry and Geology of the Autonomous University of Barcelona (UAB) as coordinators of the PhD programme in Materials Science. The authors thank Dr A. Roig, Dr A. Laromaine and Dr D. Abol-Fotouh (ICMAB-CSIC) for the CNT:cellulose sample preparation and fruitful discussions. The authors thank Dr Aleksandr Perevedentsev for his help with sample preparation, and Mr Pau Molet for his help with the FTIR measurements. We acknowledge support of the publication fee by the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI).Peer reviewe
