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Tubular hollow fibre electrodes for CO2 reduction made from copper aluminum alloy with drastically increased intrinsic porosity
Authors
Daniel Bell
Maren Großeheide
+4 more
Laura Hülsdünker
Lennart Marx
Deniz Rall
Matthias Wessling
Publication date
1 January 2020
Publisher
Amsterdam [u.a.] : Elsevier Science
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Abstract
Electrochemical reduction of CO2 to higher-order hydrocarbon products offers a significant contribution to the challenge of a circular economy. In the pursuit of better copper metal catalyst, it was early on realized that increasing productivity of copper catalysts systems is reliant on high surface area per volume. Tubular gas diffusion electrodes offer such properties. In this work, we present a methodology to fabricate tubular hollow fibre copper electrodes with drastically increased intrinsic porosity. Our described method utilizes a standard dealloying process of copper aluminium particles to induce an intra-particle nanoporosity. The specific surface area increases from 0.126 m2 g−1 before dealloying to 6.194 m2 g−1 after dealloying. In comparison to conventional planar copper electrodes and literature data from conventional copper hollow fibres, the intra-particle porosity leads to a drastically increase in electrochemical activity. Electrochemical measurements reveal increased current densities at low over-potentials in comparison to conventional copper electrodes under identical experimental conditions emphasizing the significant impact of the porosity on the electrode performance. The presented method can be easily transferred to other alloy particles, highlighting its versatility for electrode fabrication. © 2019 The Author(s
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Last time updated on 12/11/2021
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Repositorium für Naturwissenschaften und Technik (TIB Hannover)
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Last time updated on 23/07/2022