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Manganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategy
Authors
Matthias Beller
Sara Kopf
Helfried Neumann
Publication date
1 January 2021
Publisher
London : Royal Society of Chemistry (RSC)
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Abstract
A novel manganese-catalyzed C-H activation methodology for selective hydrogen isotope exchange of benzaldehydes is presented. Using D2O as a cheap and convenient source of deuterium, the reaction proceeds with excellent functional group tolerance. Highortho-selectivity is achieved in the presence of catalytic amounts of specific amines, whichin situform a transient directing group. © The Royal Society of Chemistry 2021
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Last time updated on 23/07/2022