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A thiazolo[5,4-: D] thiazole-bridged porphyrin organic framework as a promising nonlinear optical material
Authors
Bishnu P. Biswal
D. Narayana Rao
+5 more
M. Veeramohan Rao
Nabil A. Saad
Rojalin Sahu
Mahalaxmi Samal
Sreeramulu Valligatla
Publication date
1 January 2019
Publisher
London : Royal Society of Chemistry (RSC)
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Abstract
Porphyrin-based porous organic frameworks are an important group of materials gaining interest due to their structural diversity and distinct opto-electronic properties. However, these materials are seldom explored for nonlinear optical (NLO) applications. In this work, we investigate a thiazolo[5,4-d]thiazole-bridged porous, porphyrin framework (Por-TzTz-POF) with promising NLO properties. The planar TzTz moiety coupled with integrated porphyrin units enables efficient π-conjugation and charge distribution in the Por-TzTz-POF resulting in a high nonlinear absorption coefficient (β = 1100 cm GW-1) with figure of merit (FoM) σ1/σ0 = 5571, in contrast to analogous molecules and material counterparts e.g. metal-organic frameworks (MOFs; β = ∼0.3-0.5 cm GW-1), molecular porphyrins (β = ∼100-400 cm GW-1), graphene (β = 900 cm GW-1), and covalent organic frameworks (Por-COF-HH; β = 1040 cm GW-1 and FoM = 3534). This journal is © The Royal Society of Chemistry
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Last time updated on 23/07/2022