Financial support from Public Health Service Research Grant No. GM-10168 from the Division of General Medicine, PHS, is gratefully acknowledged. 1 W. B. Person, R. E. Humphrey, W. A. Deskin and A. I. Popov, J. Am. Chem, Soc. 80, 2049 (1958). 2 W. B. Person, R. E. Humphrey and A. I. Popov, J. Am Chem. Soc. 81, 273 (1959). 3 W. B. Person, R. E. Erickson and R. E. Buckles, J. Am. Chem. Soc. 82, 29 (1960). 4 H. B. Friedrich and W. B. Person, J. Chem. Phys. 44, 2161 (1966).Author Institution: Department of Chemistry, University of IowaThe infrared intensities of the Ξ½(IβCI),Ξ½(IβI) and Ξ½(DβA) vibrational bands found in charge-transfer complexes of n and Ο electron donors with I2β and ICl have been measured in benzene and n-heptane solutions. A Beckman IR-11 spectrometer was used together with a cell constructed of high density polyethylene. Pathlength calibrations have been carried out using bands of known intensity in pure liquid CHCl2βCCl4β and benzene, and it has been shown that the pathlength variation when using such a cell is sufficiently small to give good Beers Law plots and intensity values with a random error of less than Β±12. The results extend the earlier1β2 higher frequency intensity studies on complexes with Br2β,ICl and ICN. Quantitative confirmation that the intensity of the Ξ½(NβI) vibration is significantly lower than that of the Ξ½(IβCl) vibration in the pyridine-ICl complex has been obtained, indicating a smaller vibronic effect4 in the former vibration