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Structural, Magnetic, and Electrochemical Characterization of Iron(III) and Cobalt Complexes with Penta-N3O2-dentate Ligands
Authors
Roman Boca
Stephen Klimke
+6 more
Dominik Natke
Masaaki Ohba
Hiroki Oshio
Annika Preiss
Franz Renz
Takuya Shiga
Publication date
1 January 2021
Publisher
Weinheim : Wiley-VCH
Doi
Cite
Abstract
Six new mononuclear [FeIII(LBr,Cl)X]-complexes (LBr,Cl is the dianionic penta-N3O2-dentate Schiff base ligand N,N′-bis(2’-hydroxy-3-bromo-5-chlorobenzylidene)-1,6-diamino-3-azahexane; X: Cl−, N3−, NCO−, NCS−, NCSe−, CN−) were synthesized and their structures, magnetic and electrochemical properties studied. Structure analysis and magnetic measurements showed that [FeIII(LBr,Cl)CN] is in the low spin state and the other five complexes are in high spin states. Furthermore, the trinuclear mixed valent cobalt complex {[CoIII(LH,H)CN]2[CoII(1-methylimidazole)3(H2O)]} was prepared and its magnetic behavior studied. © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH Gmb
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Institutionelles Repositorium der Leibniz Universität Hannover
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Last time updated on 01/11/2022