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Recent Advances in Catalytic Hydrosilylations: Developments beyond Traditional Platinum Catalysts
Authors
Matthias Beller
Xinjiang Cui
+3 more
Leandro Duarte de Almeida
Kathrin Junge
Hongli Wang
Publication date
1 January 2021
Publisher
Weinheim : Wiley-VCH
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Cite
Abstract
Hydrosilylation reactions, which allow the addition of Si−H to C=C/C≡C bonds, are typically catalyzed by homogeneous noble metal catalysts (Pt, Rh, Ir, and Ru). Although excellent activity and selectivity can be obtained, the price, purification, and metal residues of these precious catalysts are problems in the silicone industry. Thus, a strong interest in more sustainable catalysts and for more economic processes exists. In this respect, recently disclosed hydrosilylations using catalysts based on earth-abundant transition metals, for example, Fe, Co, Ni, and Mn, and heterogeneous catalysts (supported nanoparticles and single-atom sites) are noteworthy. This minireview describes the recent advances in this field. © 2020 The Authors. Published by Wiley-VCH Gmb
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Last time updated on 23/07/2022