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Wide-Band Spectral Control Of Au Nanoparticle Plasmon Resonances On A Thermally And Chemically Robust Sensing Platform
Authors
Pieter G. Kik
Chatdanai Lumdee
Binfeng Yun
Publication date
19 September 2013
Publisher
'Information Bulletin on Variable Stars (IBVS)'
Abstract
Gold nanoparticles on Al2O3-coated gold films are presented as a chemically and thermally robust platform for molecular sensing. Single particle spectroscopy as a function of Al2O3 coating thickness shows reproducible gold nanoparticle scattering spectra in the range from 690 to 610 nm as the Al2O3 thickness increases from 0 to 3.4 nm. Numerical simulation of these structures indicates that surface-enhanced Raman spectroscopy enhancement factors in excess of 10 6 can be achieved. The stability of the Al2O 3-coated structures under high-power laser irradiation was tested, revealing stable scattering spectra upon irradiation with 100 W/mm2 at the particle resonance wavelength. The presented structure solves challenges with thermal stability, wavelength tuning range, and Raman background signal associated with previously attempted approaches. © 2013 American Chemical Society
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Last time updated on 18/10/2022