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Photophysical and electrochemical properties of the outer-sphere associate of [Ru(bipy)3]2+ with p-sulfonatothiacalix[4]arene
Authors
Antipin I.
Burilov V.
+7 more
Gubaidullin A.
Konovalov A.
Mustafina A.
Nastapova N.
Skripacheva V.
Solovieva S.
Yanilkin V.
Publication date
1 January 2008
Publisher
Abstract
1H NMR titration and X-ray diffraction analysis revealed that [Ru(bipy)3]2+ forms an outer-sphere inclusion complex with p-sulfonatothiacalix[4]arene in a ratio of 1: 1 in both aqueous solutions and the solid state. According to cyclic voltammograms and fluorimetric data, the outer-sphere association of [Ru(bipy)3]2+ with p-sulfonatothiacalix[4]arene changes the reversible character of the electrochemical oxidation of [Ru(bipy)3]2+ and lowers its emission intensity. © 2008 Springer Science+Business Media, Inc
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Last time updated on 07/05/2019