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Polarity and structure of eight-membered organosilicon compounds with planar fragments
Authors
Chachkov D.
Gazizova A.
+4 more
Ishmaeva E.
Timosheva A.
Timosheva N.
Vereshchagina I.
Publication date
1 January 2009
Publisher
Abstract
For the first time is determined the polarity of eight-membered silocyns with planar fragments. By the methods of dipole moments and theoretical calculations (DFT B3LYP/6-31G*) of 1,3,2-dioxasilocyns is established that in these compounds occurs the conformational equilibrium of the forms bath-chair and distorted bath with the predominance of the first, in this case the bonds C(sp 3)-S and C(sp 3)-H of the exocyclic MeSCH2 group are in the not eclipsed gauche orientation relative to each other. © 2009 Pleiades Publishing, Ltd
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Kazan Federal University Digital Repository
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oai:dspace.kpfu.ru:net/138551
Last time updated on 07/05/2019
Kazan Federal University Digital Repository
See this paper in CORE
Go to the repository landing page
Download from data provider
oai:dspace.kpfu.ru:net/102564
Last time updated on 07/05/2019