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优化固氮活性模型信息研究──双齿配体DPPE和DPPM对固氮酶促反应的影响
Authors
万惠霖
刘爱民
+5 more
张凤章
张鸿图
蔡启瑞
袁友珠
许良树
Publication date
30 April 1994
Publisher
Abstract
报道了某些双齿配体对固氮酶促反应影响的研究结果.发现1,2-双(二苯基磷)-乙烷(DPPE)对固氮酶酶促乙炔还原反应有促进作用,但同时又抑制了固氮酶的放氢反应。而比DPPE少一个-CH2-链的双(二苯基磷)-甲烷(DPPM)却不能表现出对固氮酶促乙炔还原活力的促进作用.对照固氮酶MoFe-蛋白X-光衍射结构分析结果和量子化学近似计算所导出的固氮酶活性中心结构模型提出了DPPE促进酶促乙炔还原反应的一种可能的解释
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Last time updated on 16/06/2016