B(C\u3csub\u3e6\u3c/sub\u3eF\u3csub\u3e5\u3c/sub\u3e)\u3csub\u3e3\u3c/sub\u3e-promoted tandem silylation and intramolecular hydrosilylation: diastereoselective synthesis of oxasilinanes and oxasilepanes

Abstract

B(C6F5)3 promotes regio- and stereoselective cyclizations of unsaturated alkoxysilanes to generate oxasilinanes and oxasilepanes. The same products are available directly from alkenols via tandem silylation and hydrosilylation