For bare lead ions, decelerated to the low beam energy of 10 MeV/u, the x-ray
emission associated with radiative recombination (RR) at "cold collision"
conditions has been studied at the electron cooler of CRYRING@ESR at
GSI-Darmstadt. Utilizing dedicated x-ray detection chambers installed at
0{\deg} and 180{\deg} observation geometry, we observed for the very first time
for stored ions the full x-ray emission spectrum associated with RR under
electron cooling conditions. Most remarkably, no line distortion effects due to
delayed emission are present in the well resolved spectra, spanning over a wide
range of x-ray energies (from about 5 to 100 keV) which enable to identify
fine-structure resolved Lyman, Balmer as well as Paschen x-ray lines along with
the RR transitions into the K-, L and M-shell of the ions. To compare with
theory, an elaborate theoretical model has been applied. By considering the
relativistic atomic structure of Pb81+, this model is based on a
sophisticated computation of the initial population distribution via RR for all
atomic levels up to Rydberg states with principal quantum number n= 165 in
combination with cascade calculations based on time-dependent rate equations.
Within the statistical accuracy, the experimental x-ray line emission is in
very good agreement with the results of the theoretical model applied. Most
notably, this comparison sheds light on the contribution of prompt and delayed
X-ray emission (up to 70 ns) to the observed X-ray spectra, originating in
particular from Yrast transitions into inner shells