SYNTHESIS, CHARACTERIZATION AND ELECTROCHEMICAL INVESTIGATION OF NOVEL 17-MEMBERED DIOXADIAZA NAPTHALDEHYDE BASED MACROCYCLIC LIGAND AND ITS COMPLEXES OF Co (III), Ni (II) AND Cu (II) PERCHLORATE IONS

Abstract

Objective: The objective of this research is to synthesis hitherto, novel unreported [17]-membered dioxadiaza napthaldehyde based macrocyclic ligand (L) and to synthesize its Co(III), Ni(II) and Cu(II) metal ion complexes.Methods: The synthesis of the ligand has been accomplished by two different synthetic routes each involving two stages. 2-Hydroxy-1-Napthaldehyde in the presence of potassium carbonate was treated with α,α'-dibromo-m-xylene to yield the dial derivative (I). The dial derivative (I) was further made to undergo Schiff base condensation with 1,2-diaminobenzene to yield the bright yellow macrocycle (L) in good yield. In the second method the Schiff base condensed product Napthaloph was synthesized and allowed to undergo Williamson's condensation with α,α'-dibromo-m-xylene to yield the ligand (L).Results: The ligand and its complexes were characterized by elemental analysis, electronic spectroscopy, IR, Conductivity measurements, EPR, magnetic susceptibility, 1H NMR and MS. The neutral seventeen membered tetradentate dioxadiaza ligand (L) readily complexes with Co(III), Ni(II) and Cu(II) perchlorate salts in 1:1 mole ratio to yield complexes of formulae [Co(L)X2]ClO4, [Ni(L)X2], [Cu(L)X]ClO4, (X = Cl-, Br-and NO3-). The complexes were also synthesized by the metal template method. The yield of the template procedure was found to be greater than the non-template method.Conclusion: A hitherto 2, 10-dioxa-21,29-diaza-heptacyclo-[29.4.2.1[4,8].0[1,32].0[11,20].0[14,19].0[23,28].0[32,37]]-tetraconta-4, 6, 8, 11, 13, 15, 17, 19, 21, 23, 25, 27, 29, 31, 33, 35, 37, 39-octatecaene. The [17]-membered tetradentate dioxadiaza macrocycle (L) was found to accommodate Co3+, Ni2+, and Cu2+ions with ease due to the presence of flexible alkyl groups. Further studies with the inner-transition metal ions will be highly informative in understanding the coordinating capabilities of lanthanides and actinides.Â