Cycloaddition of vinyl aziridines with unsaturated substrates. A novel rearrangement of an unsaturated nitro compound.

Abstract

Vinylaziridine undergoes reaction with electrophilic acetylenes and olefins to produce 7-membered azepine derivatives. With [beta]-nitro-styrene however, a novel rearrangement occurs, presumably via an ene reaction to form , the structure of which is definitively shown by x-ray diffraction.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/24586/1/0000869.pd

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