A sensitivity analysis of the parameters involved in a multiionic reactive transport model
that can be used, among other applications, to predict chloride ingress in concrete structures is
presented. The analysis is based on the calculation of the elasticity of each parameter using a
rigorous mathematical method. It was performed for two different test cases. The first
concerns the penetration of chloride ions in saturated concrete during a simple ponding
experiment while the second one involves the influence of wetting and drying cycles on
chloride ingress. The analysis indicates that porosity and tortuosity (i.e. ionic diffusion
coefficients) are the material parameters which have the most important impact on the model
predictions. Boundary conditions were also found to have a significant influence on the output
of the model. On the other hand, simulations were found to be much less affected by
parameters such as the initial pore solution chemistry and the initial solid phase content of the
hydrated cement paste