Tetragonal CuMnAs was the first antiferromagnet where reorientation of the
N\'eel vector was reported to occur by an inverse spin galvanic effect. A
complicating factor in the formation of phase-pure tetragonal CuMnAs is the
formation of an orthorhombic phase with nearly the same stoichiometry.
Pure-phase tetragonal CuMnAs has been reported to require an excess of Cu to
maintain a single phase in traditional solid state synthesis reactions. Here we
show that subtle differences in diffraction patterns signal pervasive
inhomogeneity and phase separation, even in Cu-rich Cu1.18Mn0.82As.
From calorimetry and magnetometry measurements, we identify two transitions
corresponding to the N\'eel temperature (TN) and an antiferromagnet to weak
ferromagnet transition in Cu1.18Mn0.82As and
CuMn0.964As1.036. These transitions have clear crystallographic
signatures, directly observable in the lattice parameters upon in-situ heating
and cooling. The immiscibility and phase separation could arise from a
spinoidal decomposition that occurs at high temperatures, and the presence of a
ferromagnetic transition near room temperature warrants further investigation
of its effect on the electrical switching behavior.Comment: 10 pages, 9 figures, added author middle initia