It is demonstrated that the known for a long time transition between the gap
and gapless superconducting states in the Abrikosov-Gor'kov theory of
superconducting alloy with paramagnetic impurities is of the Lifshitz type,
i.e. of the 221 order phase transition. We prove that this phase
transition has a topological nature and is characterized by the corresponding
change of the topological invariant, namely the Euler characteristic. We study
the stability of such a transition with respect to the spatial fluctuations of
the magnetic impurities critical concentration ns and show that the
requirement for validity of its mean field description is unobtrusive: ∇(lnns)≪ξ−1 (here ξ is the superconducting
coherence length) Finally, we show that, similarly to the Lifshitz point, the
221 order phase transition should be accompanied by the corresponding
singularities, for instance, the superconducting thermoelectric effect has a
giant peak exceeding the normal value of the Seebeck coefficient by the ratio
of the Fermi energy and the superconducting gap. The concept of the experiment
for the confirmation of 221 order topological phase transition is
proposed.Comment: 7 pages with the supplemental material and 3 figure