Information technology demands continuous increase of data-storage density.
In high-density magnetic recording media, the large magneto-crystalline
anisotropy (MCA) stabilizes the stored information against decay through
thermal fluctuations. In the latest generation storage media, MCA is so large
that magnetic order needs to be transiently destroyed by heat to enable bit
writing. Here we show an alternative approach to control high-anisotropy
magnets: With ultrashort laser pulses the anisotropy itself can be manipulated
via electronic state excitations. In rare-earth materials like terbium metal,
magnetic moment and high MCA both originate from the 4f electronic state.
Following infrared laser excitation 5d-4f electron-electron scattering
processes lead to selective orbital excitations that change the 4f orbital
occupation and significantly alter the MCA. Besides these excitations within
the 4f multiplet, 5d-4f electron transfer causes a transient change of the 4f
occupation number, which, too, strongly alters the MCA. Such MCA change cannot
be achieved by heating: The material would rather be damaged than the 4f
configuration modified. Our results show a way to overcome this limitation for
a new type of efficient magnetic storage medium. Besides potential
technological relevance, the observation of MCA-changing excitations also has
implications for a general understanding of magnetic dynamics processes on
ultrashort time scales, where the 4f electronic state affects the angular
momentum transfer between spin system and lattice.Comment: Manuscript (14 pages, 3 figures) and Supplementary Information (22
pages, 9 figures