Ni-Catalyzed Multi-Component Coupling Reaction of Aldimine,1,3-Diene, Alkyne, and Organozinc

Abstract

Aldimines composed of aldehydes and primary amines react with 1,3-diene,alkyne, and Me_2Zn to furnish dienyl homoallylamines in the presence of Ni catalyst.In case of Ph_2Zn, alkyne serves as a spectator ligand to promote the three-component coupling reaction of Ph_2Zn, diene, and aldimine.Nagasaki Symposium on Nano-Dynamics 2008 (NSND2008) 平成20年1月29日(火)於長崎大学 Poster Presentatio

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