We have discussed thermodynamic properties from susceptibilities and specific heat mesurements of isostructural one-dimensional M2P4O12 system. The compounds show different magnetic behaviours, varied from ferromagnetic to antiferromagnetic ordering.We have discussed thermodynamic properties from susceptibilities and specific heat mesurements of isostructural one-dimensional M2P4O12 system. The compounds show different magnetic behaviours, varied from ferromagnetic to antiferromagnetic ordering