Finite size effects on Raman spectrum of single-walled boron nitride nanotube

Abstract

Using the spectral moments method, we present calculations of Raman active modes of Single Walled Boron Nitride Nanotube (SW-BNNT). The Spectra are computed for chiral and achiral nanotubes in terms of their diameter and length. The behaviors of low frequency Raman active modes characteristic, in terms of the tube diameter revealed that these frequencies are diameter dependent. We show that the number of Raman active modes, their frequencies, and intensities depend on the length and chirality of the nanotubes. These predictions are useful to interpret the experimental Raman spectra of BNNTs.Using the spectral moments method, we present calculations of Raman active modes of Single Walled Boron Nitride Nanotube (SW-BNNT). The Spectra are computed for chiral and achiral nanotubes in terms of their diameter and length. The behaviors of low frequency Raman active modes characteristic, in terms of the tube diameter revealed that these frequencies are diameter dependent. We show that the number of Raman active modes, their frequencies, and intensities depend on the length and chirality of the nanotubes. These predictions are useful to interpret the experimental Raman spectra of BNNTs

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