Precision control of a quantum system requires accurate determination of the
effective system Hamiltonian. We develop a method for estimating the
Hamiltonian parameters for some unknown two-state system and providing
uncertainty bounds on these parameters. This method requires only one
measurement basis and the ability to initialise the system in some arbitrary
state which is not an eigenstate of the Hamiltonian in question. The scaling of
the uncertainty is studied for large numbers of measurements and found to be
proportional to one on the square-root of the number of measurements.Comment: Minor corrections, Accepted for publication in Physical Review
