Previous efforts in complex networks research focused mainly on the
topological features of such networks, but now also encompass the dynamics. In
this Letter we discuss the relationship between structure and dynamics, with an
emphasis on identifying whether a topological hub, i.e. a node with high degree
or strength, is also a dynamical hub, i.e. a node with high activity. We employ
random walk dynamics and establish the necessary conditions for a network to be
topologically and dynamically fully correlated, with topological hubs that are
also highly active. Zipf's law is then shown to be a reflection of the match
between structure and dynamics in a fully correlated network, as well as a
consequence of the rich-get-richer evolution inherent in scale-free networks.
We also examine a number of real networks for correlations between topology and
dynamics and find that many of them are not fully correlated.Comment: 16 pages, 7 figures, 1 tabl