Low-dimensional periodic arrays of scatterers with a moving point particle
are ideal models for studying deterministic diffusion. For such systems the
diffusion coefficient is typically an irregular function under variation of a
control parameter. Here we propose a systematic scheme of how to approximate
deterministic diffusion coefficients of this kind in terms of correlated random
walks. We apply this approach to two simple examples which are a
one-dimensional map on the line and the periodic Lorentz gas. Starting from
suitable Green-Kubo formulas we evaluate hierarchies of approximations for
their parameter-dependent diffusion coefficients. These approximations converge
exactly yielding a straightforward interpretation of the structure of these
irregular diffusion coeficients in terms of dynamical correlations.Comment: 13 pages (revtex) with 5 figures (postscript