Binder-Free Nickel Oxide Lamellar Layer Anchored CoO$_{x}$ Nanoparticles on Nickel Foam for Supercapacitor Electrodes

Abstract

To enhance the connection of electroactive materials/current collector and accelerate the transport efficiency of the electrons, a binder-free electrode composed of nickel oxide anchored CoO$_{x}$ nanoparticles on modified commercial nickel foam (NF) was developed. The nickel oxide layer with lamellar structure which supplied skeleton to load CoO_{x) electroactive materials directly grew on the NF surface, leading to a tight connection between the current collector and electroactive materials. The fabricated electrode exhibits a specific capacitance of 475 F/g at 1 mA/cm$^{2}$. A high capacitance retention of 96% after 3000 cycles is achieved, attributed to the binding improvement at the current collector/electroactive materials interface. Moreover, an asymmetric supercapacitor with an operating voltage window of 1.4 V was assembled using oxidized NF anchored with cobalt oxide as the cathode and activated stainless steel wire mesh as the anode. The device achieves a maximum energy density of 2.43 Wh/kg and power density of 0.18 kW/kg, respectively. The modified NF substrate conducted by a facile and effective electrolysis process, which also could be applied to deposit other electroactive materials for the energy storage device