Hierarchical AlSBA-15–zeolite materials were utilized as a supports for preparing hydroisomerization catalysts. Detailed consideration was given to: (i) the effect of the zeolite type introduced into AlSBA-15–zeolite composites (where zeolite is β, mordenite or ZSM-5) as well as (ii) the promotion effect of Pd addition. The composites showed higher activity in isomerization as compared to Pt/AlSBA-15. The enhanced isomerization efficiency were explained by the appropriate metallic and acidic function as well as suitable transport properties. The modification of the hydrogenating function by Pd incorporation increases the hydroisomerization efficiency of Pt-Pd/AlSBA-15–β catalyst. Over bimetallic Pt-Pd/AlSBA-15–β, the high yields of isomers (68 wt%) with respect to 50 wt% for a control catalyst. The most promising Pt-Pd/AlSBA-15–β catalyst allows to improve research octane number from 0 to the 74 value
