In traditional Global Navigation Satellite System (GNSS) application, the reflected GNSS signals from Earth’s surface generally are considered as an interference source to be suppressed or removed. Recently, a new idea which treats the reflected GNSS signal as opportunity source of remote sensing has been proposed to monitor Earth’s physical parameters. This technique is called as GNSS-Reflectometry (GNSS-R) which has the advantages of low-power, -mass and -cost. With the development and modernization of GPS, Galileo, GLONASS, and BeiDou system, spaceborne GNSS could significantly improve the temporal-spatial resolution by receiving and processing the reflected signal from multiple satellites. This chapter mainly describes this new bi-static remote sensing technique. First, basic theories of GNSS-R including spatial geometry, polarization, and scattering model of reflected signal are discussed; second, spaceborne receivers and fast-response processing methods are reviewed and analyzed; finally, the empirical models retrieving wind speed are proposed and demonstrated using the DDM data from the UK-TechDomeSat-1 satellite. Based on the discussion of this chapter, it could be concluded that although GNSS-R still has some key challenges which have to be addressed, it could be an optimal choice of remote sensing in some special conditions, such as the tropical cyclone