This paper presents an analysis of some experimental results concerning micro-structural tests, permeability measurements and strain-stress tests of four types of High-Performance Concrete, exposed to elevated temperatures (up to
700∘C). These experimental results, obtained within the "HITECO" research programme are discussed and interpreted in the context of a recently developed mathematical model of hygro-thermal behaviour and degradation of concrete at high temperature, which is briefly presented in the Part 2 paper (Gawin, et al. 2005). Correlations between concrete permeability and porosity micro-structure, as well as between damage and cracks' volume, are found. An approximate decomposition of the thermally induced material damage into two parts, a chemical one related to cement dehydration process, and a thermal one due to micro-cracks' development caused by thermal strains at micro- and meso-scale, is performed. Constitutive relationships describing influence of temperature and material damage upon its intrinsic permeability at high temperature for 4 types of HPC are deduced. In the Part II of this paper (Gawin, et al. 2005) effect of two different damage-permeability coupling formulations on the results of computer simulations concerning hygro-thermo-mechanical performance of concrete wall during standard fire, is numerically analysed